煤炭工程 ›› 2020, Vol. 52 ›› Issue (1): 138-142.doi: 10.11799/ce202001028

• 研究探讨 • 上一篇    下一篇

新型CPAM合成及其在煤泥水处理中的应用研究

赵翔,黄波,刘国伟   

  1. 中国矿业大学(北京)
  • 收稿日期:2019-05-07 修回日期:2019-07-01 出版日期:2020-01-10 发布日期:2020-05-13
  • 通讯作者: 赵翔 E-mail:zhao928743213@163.com

Synthesis of New CPAM and Its Application in Coal Slime Water Treatment

  • Received:2019-05-07 Revised:2019-07-01 Online:2020-01-10 Published:2020-05-13

摘要: 采用丙烯酰胺(AM)为分子骨架,丙烯酰氧乙基三甲基氯化铵(DAC)和甲基丙烯酸二甲氨基乙酯(DMAEMA)为阳离子单体,通过水溶液聚合的方法,合成一种新型有机高分子材料——阳离子絮凝剂PADD。并确定其合成的最佳反应条件:pH=3,聚合反应温度为30℃,反应单体质量分数为25%,引发剂过硫酸钠(Na2S4O8)和亚硫酸钠(Na2SO3)质量分数均为0.10%,药剂单体用量配比为40∶30∶30,聚合反应时间为6h。之后用粘度法测定产物特性粘度并计算了产物的相对分子质量,运用红外光谱对聚合物结构进行分析与表征,使用合成的絮凝剂对选煤厂煤泥水进行絮凝沉降试验,研究其絮凝性能。

关键词: 丙烯酰胺, 阳离子有机高分子絮凝剂, 丙烯酰氧乙基三甲基氯化铵, 甲基丙烯酸二甲氨基乙酯

Abstract: Abstract: In this paper, acrylamide (AM) is used as molecular skeleton, acrylamide ethyl three methyl ammonium chloride (DAC) and dimethyl methacrylate (DMAEMA) are cationic monomers, and a new type of organic polymer material is synthesized by aqueous solution polymerization Cationic flocculant PADD. And determine the optimum reaction conditions for its synthesis: pH=3, polymerization temperature of 30 ℃, reaction monomer mass fraction 25%, initiator sodium sulfate (Na2S4O8) and sodium sulfite (Na2SO3) quality fraction of 0.1%, The dosage ratio of medicament monomer was 40:30:30, and the polymerization time was 6h. Afterwards, the viscosity of the product was determined by viscosity method and the relative molecular mass of the product was calculated, the polymer structure was analyzed and characterized by infrared spectroscopy, and the flocculation and sedimentation of coal slurry in preparation plant was studied by using synthetic flocculant.

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