Abstract: This paper Uses the relevant data of 2013-2018, inspects the coal industry with the method of canonical correlation analysis of the relationship between social responsibility and corporate value. Results show that the coal industry listed companies highly related to the enterprise value and social responsibility, and should enhance shareholder returns, guarantee the delinquency, protecting the legal rights and interests of consumers and employees, to achieve the mutual promotion between the two, and finally to the coal industry and provides the theory basis for relevant enterprises social responsibility in the face, and give the related Suggestions.