煤炭工程 ›› 2024, Vol. 56 ›› Issue (12): 205-212.doi: 10.11799/ce202412030

• 研究探讨 • 上一篇    下一篇

水煤浆气化粗渣制备泡沫材料及其吸波性能研究

谷红伟   

  1. 国能销售集团有限公司
  • 收稿日期:2024-04-03 修回日期:2024-07-08 出版日期:2024-12-20 发布日期:2025-01-08
  • 通讯作者: 谷红伟 E-mail:277873301@qq.com

Preparation of lightweight materials from coarse slag gasification of coal-water slurry and its absorption properties

Gu Hongwei   

  • Received:2024-04-03 Revised:2024-07-08 Online:2024-12-20 Published:2025-01-08
  • Contact: Gu Hongwei E-mail:277873301@qq.com

摘要: 水煤浆气化粗渣颗粒经过高温焙烧后出现发泡黏结现象,为利用其制备泡沫材料提供了基础。以宁东四喷嘴水煤浆气化粗渣为原料,采用单一变量法依次探究了粗渣用量、焙烧温度、保温时间对泡沫材料抗压强度和体积密度的影响。结果表明,在粗渣粒度为1.25~5 mm,粗渣用量为14 g(固定容积的模具),焙烧气氛为N2,焙烧温度为750 ℃,保温时间为10 min的条件下,制备出的泡沫材料的抗压强度高于1.5 MPa,体积密度低于0.5 g/cm3。该材料的电磁波吸收性能为:当材料厚度为7 mm时,最低反射损耗值为-22.14 dB(16.80 GHz),有效带宽为1.88 GHz。它对电磁波的吸收主要体现在16~18 GHz频段,吸收损耗机制以气化渣中丰富铁氧体的磁损耗作用为主。可为水煤浆气化粗渣在泡沫材料的制备及其在吸波领域的应用提供新的思路。

关键词: 水煤浆气化粗渣, 发泡, 轻质, 成型, 电磁波

Abstract: The foaming and bonding phenomenon occurs in the coarse slag particles of coal water slurry gasification after high temperature roasting, which provides a basis for the preparation of foam materials. In this paper, the single variable method is used to explore the effects of slag amount, roasting temperature and holding time on the compressive strength and volume density of foam materials, using Ningdong four nozzle coal water slurry gasification slag as raw material. The results show that, under the conditions of 1.25mm~5mm coarse slag particle size, 14g coarse slag amount (fixed volume mold), N2 roasting atmosphere, 750°C roasting temperature and 10min holding time, the compressive strength of the prepared foam material is higher than 1.5MPa, and the volume density is lower than 0.5g/cm3. The electromagnetic wave absorption performance of the material is: when the material thickness is 7mm, the minimum reflectance loss value is -22.14db (16.80GHz), and the effective bandwidth is 1.88GHz. Its absorption of electromagnetic waves is mainly reflected in the 16~18GHz frequency band, and the absorption loss mechanism is mainly the magnetic loss effect of ferrite in the gasification slag. It can provide new ideas for the preparation of foam materials and the application of foam materials in the field of electromagnetic wave absorption.