煤炭工程 ›› 2016, Vol. 48 ›› Issue (11): 115-119.doi: 10.11799/ce201611033

• 研究探讨 • 上一篇    下一篇

褐煤弱氧化改质脱水水质对比分析

王小华1,赵洪宇1,李玉环2,宋强3,吕俊鑫1,舒新前1   

  1. 1. 中国矿业大学(北京)
    2. 内蒙古工业大学
    3. 中国矿业大学(北京)化学与环境工程学院
  • 收稿日期:2016-08-08 修回日期:2016-09-04 出版日期:2016-11-10 发布日期:2016-12-16
  • 通讯作者: 赵洪宇 E-mail:yuyu_3003@126.com

The analysis of quality of water after weak oxidation and thermal upgrading at low tempereture

  • Received:2016-08-08 Revised:2016-09-04 Online:2016-11-10 Published:2016-12-16

摘要: 为实现褐煤提质并解决褐煤主产地干旱缺水问题,采用自行设计的固定床反应器及电感耦合等离子体质谱(ICP-MS)对锡林郭勒褐煤进行不同干燥介质脱水并对冷凝水水质进行对比分析,同时对不同干燥温度下的煤样在干燥过程中产生的气体产率也进行了研究。结果表明:两种不同粒径煤样随着干燥时间延长,煤样含水率逐渐降低,且脱水温度越高,含水率越低。相同干燥条件下,0.5~0mm煤样冷凝水中COD、BOD、NH3-N和TON值略大于6~3mm煤样。四种重金属离子的析出量均随着脱水温度的升高而逐渐增大,但煤样干燥冷凝水中重金属离子含量远低于地表水环境质量V类标准基本项目标准限值。氧气作为干燥介质时,CO2和CO的产生除了煤样自身发生分解之外,另一部分CO2和CO的产生来自煤样在干燥过程中发生的弱氧化反应。

关键词: 褐煤脱水, 水质分析, 重金属, 低温氧化, 气体产率

Abstract: In order to achieve the upgrading of lignite and solve the problem of drought and water shortage in main producing area of lignite, the water quality of condensed water with different drying media were carried out with a fixed bed reactor and an inductively coupled plasma mass spectrometry. The gas production rate of coal samples under different drying temperature was also analyzed. The results indicate that two different particle size of coal samples with extended drying time, moisture content of coal sample reduced gradually, and dehydration temperature is higher, the lower the moisture content. Some small molecular compounds in the structure of the coal molecules are partially pyrolysis with the increase of the dehydration temperature, leading to the content of COD in condensate water was produced from dry coal sample with particle size of 6 to 3 mm under the atmosphere of oxygen at 140℃ was 230mg/L. With the increase of the dehydration temperature to 280℃, the content of COD in condensate water of dry coal sample increased rapidly to 37800mg/L. The values of COD, BOD, NH3-N and TON in condensate water was produced from dry coal sample with particle size of 0.5 to 0 mm are slightly larger than 6 ~ 3mm coal samples under the same drying conditions.Four kinds of heavy metal ions in condensate water as the dehydration temperature rises, the amount of precipitation were increased gradually. However, the content of heavy metal ions in the condensate water is much lower than that of the surface water environment quality standard V. When oxygen is used as a drying medium, the CO2 and CO are produced in addition to the decomposition of the coal sample itself, and the other part of CO2 and CO are produced from the weak oxidation reaction of coal samples during the drying process.

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