煤炭工程 ›› 2017, Vol. 49 ›› Issue (1): 123-126.doi: 10.11799/ce201701036

• 研究探讨 • 上一篇    下一篇

微生物絮凝剂GSY-9对烟煤煤泥水的絮凝机理研究

王伟1,杨志超1,刘生玉2   

  1. 1. 太原理工大学矿业工程学院
    2. 太原理工大学
  • 收稿日期:2016-09-05 修回日期:2016-10-24 出版日期:2017-01-09 发布日期:2017-04-13
  • 通讯作者: 杨志超 E-mail:yangzhichao@tyut.edu.cn

Analysis on bioflocculant GSY-9 and flocculation mechanism of bituminous coal slurry

  • Received:2016-09-05 Revised:2016-10-24 Online:2017-01-09 Published:2017-04-13

摘要: 以煤泥水为絮凝对象,研究了煤泥水浓度、絮凝剂用量及pH值对圆褐固氮菌所产絮凝剂GSY-9絮凝效果的影响。结果表明:絮凝剂GSY-9对高浓度煤泥水具有较高的絮凝活性|当煤泥水浓度为30g/L,絮凝剂用量为80mg/L时,煤泥水絮凝率可达8293%|pH值在20~80范围内,其具有良好的絮凝活性。红外光谱分析表明絮凝剂GSY-9主要成分为多糖和蛋白质。煤泥伴生矿物悬浮液絮凝实验表明絮凝剂GSY-9对三种矿物的絮凝效果为高岭土>伊利石>石英|在矿物表面吸附率测定进一步验证了其对高岭土和伊利石的絮凝效果远优于石英。Zeta电位测定表明絮凝剂GSY-9分子带负电,与三种矿物的絮凝作用不是以电中和机理为主,而是以吸附架桥为基础的。

关键词: 微生物絮凝剂, 煤泥水, Zeta电位, 吸附率

Abstract: With coal slime water as the research object and studied the flocculation effect on the concentration coal slime water, flocculant dosage and pH for bioflocculant GSY-9 which was produced by azotobacter chroococcum. The results show that flocculation activity is at its highest when the following conditions are met: slime water concentration 30 g/L and a flocculant concentration of 80 mg/L. The flocculation activity can be up to 82.93% of bioflocculant at the time. Flocculant GSY-9 kept the high flocculation activity at the range of pH 2.0~8.0.The main components of bioflocculant GSY-9 were polysaccharide and protein through the analysis of FTIR. Flocculation experiment of the coal associated minerals indicate that the order of flocculent effect from large to small for bioflocculant GSY-9 on the three kinds of mineral is kaolin, illite and quartz. The further experiment of absorption rate for bioflocculant GSY-9 on miners was showed that the flocculent effect of kaolin and illite were far superior to quartz. Zeta potential curve of minerals indicate that bioflocculant is partly composed of anion groups and its flocculating function is based on bridge not on the neutralizing charge.

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