煤炭工程 ›› 2022, Vol. 54 ›› Issue (12): 181-186.doi: 10.11799/ce202212032

• 研究探讨 • 上一篇    下一篇

煤泥性质及其混凝剂作用下的沉降试验研究

张迁,尹禹琦,许普查   

  1. 1. 国家能源集团宁夏煤业有限责任公司洗选中心
    2. 黑龙江科技大学
  • 收稿日期:2022-11-04 修回日期:2022-11-24 出版日期:2022-12-14 发布日期:2023-02-06
  • 通讯作者: 张迁 E-mail:2842299578@QQ.COM

Experimental Study on the Properties of Coal Slime and Its Sedimentation under the Action of Coagulant

  • Received:2022-11-04 Revised:2022-11-24 Online:2022-12-14 Published:2023-02-06
  • Contact: zhang qianqian E-mail:2842299578@QQ.COM

摘要: 针对宁东枣泉选煤厂煤泥难沉降问题,首先对其煤泥进行测试分析,揭示了其难沉降原因,之后通过沉降试验深入研究了不同种类的凝聚剂、絮凝剂及其联合作用对煤泥沉降效果的影响,并优选出煤泥水处理的最优凝聚剂和絮凝剂联合使用配方。煤泥测试结果表明,该煤泥空气干燥基灰分高达46.15%,含有一定量的高岭石和蒙脱石,易泥化|煤泥颗粒表面含有较多含氧官能团,有一定的亲水性|Zeta电位为-32.47mV,煤泥水中的固体颗粒之间有较强的静电斥力,导致煤泥沉降困难。煤泥水沉降试验发现,凝聚剂聚合氯化铝(PAC)单独使用效果优于聚合硫酸铝(PAS)和聚合硫酸铁(PFS),且PAC用量为15kg/t时煤泥水沉降效果最佳|聚丙烯酰胺类絮凝剂阳离子型(CPAM)单独使用效果优于阴离子型(APAM)、两性离子型(ACPAM)和非离子型NPAM,且CPAM最佳用量为150g/t|当CPAM添加量为150g/t,PAC添加量为10kg/t联合使用时,煤泥水沉降效果最好,此时综合指标为1.26cm/(s·NTU)。

关键词: 煤泥沉降, 絮凝剂, 凝聚剂, 工业分析

Abstract: The industrial analysis and instrumental characterization of coal slime from a coal preparation plant in Ningdong were carried out, and the effects of different flocculants, flocculants and their combination on slime sedimentation were studied. The results show that the ash content of the coal slurry is as high as 47.58%, which contains a certain amount of kaolinite and montmorillonite. There are more oxygen-containing functional groups in the slime, and it has certain hydrophilicity, and the Zeta potential is -32.47 mV. There is strong electrostatic repulsion between the solid particles in the slime water, and the slime water system is stable and not easy to settle. Secondly, in slime water sedimentation test, the effect of PAC is better than PAS and PFS, and the best effect is when the dosage of PAC is 15kg/T. The effect of flocculant CPAM is better than Apam, ACPAM and NPAM. The optimum dosage of CPAM is 150g/t. When PAC and CPAM are used together, when the amount of CPAM is 150g/t and the amount of PAC is 10kg/t, the comprehensive index of slime water is the highest. The settling velocity of coal slurry is 0.65 cm·S-1, the turbidity of supernatant is 44.26 NTU, the floc height is 3.57 cm, and the comprehensive index is 1.26 cm·s-1·NTU-1.

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