煤炭工程 ›› 2024, Vol. 56 ›› Issue (3): 197-204.doi: 10.11799/ce202403029

• 研究探讨 • 上一篇    下一篇

粗糙度对贫瘦煤表面润湿性的影响

熊鹏,董宪姝,叶贵川,等   

  1. 1. 太原理工大学
    2. 太原理工大学虎峪校区
  • 收稿日期:2023-05-23 修回日期:2023-07-20 出版日期:2024-03-20 发布日期:2024-03-25
  • 通讯作者: 董宪姝 E-mail:dxshu520@163.com

Effect of roughness on surface wettability of lean coal

  • Received:2023-05-23 Revised:2023-07-20 Online:2024-03-20 Published:2024-03-25

摘要: 表面粗糙度对煤的可浮性起着重要作用。为了研究捕收剂和粗糙度协同作用对煤表面润湿性的影响, 采用四种不同目数的砂纸对煤表面进行粗糙化处理, 并使用粗糙度测量仪表征其表面特性。采用接触角与相互作用测量仪分析表面粗糙度对煤天然润湿性和油酸钠改性后润湿性的影响。结果表明, 随着天然煤表面粗糙度的增加, 接触角减小。由于接触线的增加, 水滴与煤表面之间的扩散力增大。当粗糙度分别为0. 32、1. 02、1. 82、2. 38 μm 时, 水与煤表面之间的扩散力分别为159. 00、177. 82、200. 99、209. 60 μN。而经低浓度(120 mg/ L) 油酸钠改性后, 随着粗糙度的增加, 煤表面的接触角增大, 扩散力减小, 扩散力分别为149. 11、146. 40、134. 06、124. 27 μN。但当油酸钠浓度达到320 mg/ L 时, 随着粗糙度的增加, 接触角反而迅速减小, 扩散力迅速增大, 扩散力分别为174. 21、211. 05、244. 37、288. 51 μN。粗糙度的增大会增加天然煤表面的润湿性, 低浓度的油酸钠改性和表面粗糙化可提高煤表面疏水性, 然而, 过量的药剂会增强煤表面的润湿性。

关键词: 煤泥浮选, 表面粗糙度, 扩散力, 接触角, 疏水性

Abstract: Surface roughness directly affects the mineral surface and water action and plays an important role in the flotation of minerals. There are many studies on the relationship between mineral surface roughness and wettability, but the results are not uniform. In this study, a series of coal flakes with different surface roughness were prepared using sandpaper of different grit sizes and their surface properties were characterised using, for example, contact angle and interaction force measurements. The effect of roughness on the surface wettability of the coals was analysed with the aid of the Wenzel wettability model. The contact angle results show that the contact angle decreases with increasing surface roughness of the coal sample, indicating an increase in hydrophilicity of the coal surface, which may be due to the surface microstructure making it easier for water molecules to enter the surface defects. Spreading and residual force measurements showed that the spreading and residual force of water droplets on the coal surface increased as the roughness increased. As the roughness increased from 0.32 μm to 2.38 μm, the droplet spreading force increased from 159.00 μN to 209.60 μN and the residual force of the droplet increased from 20.74 μN to 23.64 μN. The contact angle and force measurements were consistent, meaning that increasing roughness increased the hydrophilicity of the coal surface and had a detrimental effect on flotation separation.

中图分类号: