煤炭工程 ›› 2019, Vol. 51 ›› Issue (11): 148-153.doi: 10.11799/ce201911032

• 研究探讨 • 上一篇    下一篇

超声处理对显微组分浮选分离及热解影响研究

武乐鹏1,宋强2,舒新前2   

  1. 1. 山西工程职业学院
    2. 中国矿业大学(北京)
  • 收稿日期:2019-07-11 修回日期:2019-08-25 出版日期:2019-11-20 发布日期:2020-05-11
  • 通讯作者: 武乐鹏 E-mail:524780295@qq.com

Effect of Ultrasound Treatment on Flotation Separation of Coal Maceral and Its Pyrolysis Characteristic

  • Received:2019-07-11 Revised:2019-08-25 Online:2019-11-20 Published:2020-05-11

摘要: 为了考察捕收剂、起泡剂及超声频率对煤有机显微组分中镜质组富集率影响,在实验室自制反应装置上进行了单因素实验和响应面实验,并通过SEM、FTIR和TG等分析了超声处理前后煤的表面形貌和热解特性。实验结果表明,当在捕收剂用量为0.9g/L,起泡剂用量为0.11g/L,超声频率为100kHz时,获得最大的镜质组富集率,为76.98%|响应面实验预测的最大镜质组富集率为79.27%|超声处理使煤粒表面矿物质得以清洗,热重分析表明,超声处理后浮选精煤镜质组失重率降低,而尾煤惰质组变化不大。显微组分的红外分析表明,镜质组含氧官能团特征峰振动强度大于惰质组,而惰质组的芳香含量较高。

关键词: 煤, 显微组分, 浮选, 热解

Abstract: In order to investigate the effect of collector, foaming agent and ultrasound frequency on enrichment rate of vitrinite. Single factor experiments and response surface experiments were carried out with a self-designed ultrasound flotation device, the surface morphology and pyrolysis characteristics of flotation concentrate were explored by SEM, FTIR and TGA analysis. Research results shown that when the collector, foaming agent and ultrasonic frequency was 0.9g/L, 0.11g/L and 100KHz, the enrichment rate of vitrinite reached a maximum of 76.98%. The response surface experiments shown that the enrichment rate of vitrinite could reached a maximum of 79.27%. Ultrasound treatment reduced the surface minerals of coal, and the TG analysis shown that ultrasound treatment decreased the weight loss and the rate of weight loss of vitrinite, while had no significant impact on inertinite. FTIR shown that oxygen-containing functional groups of vitrinite was higher than that of inertinite, while aromatic hydrocarbon of was less than that of inertinete.

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