煤炭工程 ›› 2022, Vol. 54 ›› Issue (12): 128-134.doi: 10.11799/ce202212023

• 研究探讨 • 上一篇    下一篇

锚杆锚索在模拟矿井水中腐蚀速率试验研究

开采研究院1,褚晓威2   

  1. 1. 开采研究院
    2. 中国煤炭科工集团天地科技股份有限公司开采设计事业部
  • 收稿日期:2022-09-15 修回日期:2022-11-15 出版日期:2022-12-14 发布日期:2023-02-06
  • 通讯作者: 褚晓威 E-mail:chuxiaowei2003@163.com

Experimental study on corrosion rate of rockbolts and cables in simulated mine water

  • Received:2022-09-15 Revised:2022-11-15 Online:2022-12-14 Published:2023-02-06

摘要: 针对锚杆锚索在矿井水中易发生腐蚀并导致力学性能下降或失效问题,采用化学成分分析、显微结构观察、电化学试验等手段,测试了热轧335、热轧500、热处理600、热处理700四种锚杆以及1860MPa级锚索的基本特性,分析了其在模拟矿井水溶液中的电化学特性和腐蚀速率。研究表明:①测试的锚杆锚索材料极化特征相似,均为活性溶解状态;②在模拟矿井水溶液中热处理600锚杆腐蚀速率最低、热轧500锚杆最高,平均腐蚀速率约为0.2mm/a,热轧锚杆的平均腐蚀速率约为热处理锚杆的1.5倍|锚索的腐蚀速率约为锚杆的十分之一;③矿井水pH值对锚杆锚索腐蚀速率影响较为显著,在pH=2强酸性条件下腐蚀速率最大,在pH=5弱酸性条件下腐蚀速率降为强酸性下的20%左右,pH=5~11区间即弱酸、中性及碱性条件下腐蚀速率总体呈小幅度下降;④Cl-浓度对锚杆锚索腐蚀速率也有影响,当Cl-浓度由0.906mmol/L增大到90.6mmol/L过程中,四种锚杆腐蚀速率均逐渐降低|当Cl-浓度增大到906mmol/L后,热轧锚杆腐蚀速率继续下降,而热处理锚杆腐蚀速率则开始增大。在100倍Cl-浓度溶液中锚索腐蚀速率增加13.35%。

关键词: 锚杆锚索, 矿井水, 均匀腐蚀, 腐蚀速率, 电化学特性

Abstract: Rockbolts and cables were prone to corrosion affected by mine water, which usually lead to the degradation of mechanical properties and failure. The basic properties, electrochemical characteristics and corrosion rates of hot-rolled 335, hot-rolled 500, heat-treated 600, heat-treated 700 rockbolts and 1860MPa cables in simulated highly-mineralized mine water were tested and analyzed by chemical composition analysis, microstructure observation and electrochemical tests. The main conclusions were as follows: ①The polarization characteristics of rockbolts and cables tested were active dissolved similarly.②In the simulated corrosive solution, the corrosion rate of heat-treated 600 was the lowest and hot-rolled 500 the highest, with an average corrosion rate of 0.2mm/a. The average corrosion rate of hot-rolled rockbolts was about 1.5 times that of heat-treated ones. The corrosion rate of cable was about one tenth of that of rockbolt.③The pH of mine water had a significant effect on rockbolt corrosion rate, which reached the maximum in pH=2.When pH=5, the corrosion rate decreased to about 20% of that in pH=2. When in pH=5-12, namely weak acid, neutral and alkaline solutions, the corrosion rate decreased slightly in general.④Cl- concentration had certain influence on the corrosion rate of bolt. The corrosion rates of the four rockbolts decreased gradually when Cl- concentration increased from 0.906mmol/L to 90.6mmol/L. When increased to 906mmol/L, the corrosion rate of hot-rolled rockbolt continued to decrease, while that of heat-treated rockbolt began to increase. The corrosion rate of cable increased by 13.35% in 100 times Cl- concentration solution.

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