煤炭工程 ›› 2022, Vol. 54 ›› Issue (10): 171-175.doi: 10.11799/ce202210032

• 研究探讨 • 上一篇    下一篇

不同粒度泥岩颗粒的分散剂优选研究

张双源,王平,刘子亮,等   

  1. 1. 中联煤层气国家工程研究中心有限责任公司
    2. 中国矿业大学(北京) 地球科学与测绘工程学院
    3. 中国矿业大学(北京)地球科学与测绘工程学院
  • 收稿日期:2022-07-11 修回日期:2022-07-25 出版日期:2022-10-14 发布日期:2023-01-06
  • 通讯作者: 魏迎春 E-mail:wyc@cumtb.edu.cn

Research of Dispersant Optimization of Mudstone Particles with Different Particle Sizes

  • Received:2022-07-11 Revised:2022-07-25 Online:2022-10-14 Published:2023-01-06

摘要: 为查明分散剂类型对不同粒度泥岩颗粒悬浮液分散效果的影响,选用韩城区块太原组11#煤层顶板泥岩样品,开展了不同粒度泥岩颗粒的分散剂优选实验,分析了不同分散剂实验条件下的泥岩颗粒悬浮液静态稳定性和质量浓度特征,探讨了分散剂对泥岩颗粒的分散稳定性的影响。实验结果表明:随泥岩颗粒粒度增大,十二烷基硫酸钠(SDS),十二烷基苯磺酸钠(SDBS)分散剂的泥岩颗粒悬浮液分散稳定性均变差|萘磺酸钠(SN)分散剂的泥岩颗粒悬浮液分散稳定性变化不明显。随静置时间增加,不同分散剂泥岩颗粒悬浮液分散稳定性降低,不同分散剂的泥岩颗粒悬浮液质量浓度均不同程度降低。SDS分散剂的泥岩颗粒悬浮液在不同粒度、不同静置时间条件下泥岩颗粒质量浓度最大。SDS具有的直链烷烃疏水基更易吸附于泥岩颗粒表面,对三种粒度的泥岩颗粒均能起到很好的分散效果,建议在煤层气洗井工艺中选择SDS作为分散剂。

关键词: 煤层气, 洗井工艺, 泥岩颗粒, 煤粉, 分散剂, 十二烷基硫酸钠

Abstract: The output of coal fines is one of the key issues affecting the efficient development of CBM. The blockage of coal fines will cause the pump to be buried and stuck in the CBM well, increase the number of workover operations in the drainage and production of the CBM well, and affect the efficient development of the CBM well. Since the content of inorganic minerals in the coal fines produced by the coalbed methane wells is as high as 50%, in order to find out the effect of different dispersant types on the dispersion of mudstone particle suspensions with different particle sizes, the Taiyuan Formation of the Hancheng block in the eastern margin of the Ordos Basin was selected. 11# coal seam roof mudstone sample, carried out the dispersant optimization experiment of mudstone particles with different particle sizes, analyzed the static stability and mass concentration characteristics of mudstone particle suspensions with different dispersants, and discussed the effect of dispersants on mudstone particles with different particle sizes and different dispersants. Effects on the dispersion stability of mudstone particles of the same size. Optimizing dispersants with relatively good dispersing effect applied to CBM well-washing technology. The experimental results show that different dispersants have different effects on the dispersion stability of mudstone particles with different particle sizes. With the increase of particle size, the dispersion stability of mudstone particle suspension of SDS and SDBS dispersants becomes worse; the dispersion stability of mudstone particle suspension of SN dispersant does not change significantly. With the increase of standing time, the dispersion stability of mudstone particle suspensions with different dispersants decreases, and the mass concentrations of mudstone particle suspensions with different dispersants all decrease to varying degrees. The mudstone particle suspension of SDS dispersant has the largest mass concentration of mudstone particles under the conditions of different particle sizes and different standing times. The straight-chain alkane hydrophobic base of SDS is more easily adsorbed on the surface of mudstone particles, which can play a good dispersion effect on mudstone particles of three sizes, and has strong suspension dispersion effect and static stability. Based on the differences in the dispersion and suspension stability of coal fines and mudstone particles with different types of dispersants, it is suggested that SDS should be selected as the dispersant in the CBM well-washing technology.

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