煤炭工程 ›› 2020, Vol. 52 ›› Issue (3): 147-151.doi: 10.11799/ce202003030

• 研究探讨 • 上一篇    下一篇

非离子型表面活性剂强化低阶煤煤泥浮选行为试验研究

张春泉,张海军,徐明,甄坤坤   

  1. 1. 国家煤加工与洁净化工程技术研究中心
    2. 中国矿业大学化工学院
    3. 中国矿业大学南湖校区化工学院
  • 收稿日期:2019-09-19 修回日期:2019-11-27 出版日期:2020-03-10 发布日期:2020-05-11
  • 通讯作者: 张春泉 E-mail:271810753@qq.com

Enhanced flotation performance for the?purification?of?low rank coal slime with the addition of non-inoic surfactant

  • Received:2019-09-19 Revised:2019-11-27 Online:2020-03-10 Published:2020-05-11

摘要: 选取非离子型表面活性剂TX-100来探究其对低阶煤浮选行为的影响。试验结果表明,随着TX-100浓度(0g/t,50g/t,100g/t,150g/t,200g/t)的逐渐增加,可燃体回收率从54.42%增加到89.43%。此外,对不同浓度TX-100处理过的煤样进行了接触角和润湿热分析,最高TX-100浓度(200g/t)处理过的煤样接触角增加了13.7°,润湿热降低了8.031J/g|使用XPS 和FTIR方法进一步探究了TX-100处理前后煤样表面性质的变化,发现TX-100处理后低阶煤表面亲水性官能团羧基(—COOH)和羟基(—OH)的含量显著减少。

关键词: 低阶煤, TX-100, 浮选动力学, 润湿热

Abstract: Abstract:Flotation is one of the most effective methods in seperation of fine minerals particals. The correct way to choose regents in flotation is the key step to improve flotation proformance and reinforce the process of concentration recovery. In this study, non-inoic surfactant TX-100 whose characters would be investigate in flotation was selected duing the process of low rank coal flotation. The increasing ultimate combustible recovery values of low rank coal which were treated with a gradual increase in concentration of TX-100 (0 g/t, 50 g/t, 100 g/t, 150 g/t, 200 g/t) from 54.42% to 89.43% demostrated that flotation performance of low rank coal acquired improvement. Besides, contact angle and wetting heat measurements were employed to analyse coal samples treated by different concentrations of TX-100, the increase of contact angle by 13.7°and decrease of wetting heat by 8.031 J/g revealed that the hydrophobic of low rank coal improved effectively which brought about good results on flotation of low rank coal. The changes in surface property of low rank coal before and after treatment were observed through XPS and FTIR measurements in order to investigate the microscopic mechanism of TX-100 on the outstanding improvement of flotation performance, it can be found that the content of carboxyl grouphydroxyl (-COOH) and hydroxyl (-OH) belonged to the hydrophilic groups decreased with the addition of TX-100.

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