煤炭工程 ›› 2024, Vol. 56 ›› Issue (12): 199-204.doi: 10.11799/ce202412029

• 研究探讨 • 上一篇    下一篇

复合酯类捕收剂浮选低阶煤试验研究

焦小淼   

  1. 煤炭科学研究总院有限公司
  • 收稿日期:2024-01-03 修回日期:2024-02-24 出版日期:2024-12-20 发布日期:2025-01-08
  • 通讯作者: 焦小淼 E-mail:jiaoxiaomiao@126.com

The Mechanism of Mixed Ester Collectors in Coal Flotation of Low-Rank Coal

  • Received:2024-01-03 Revised:2024-02-24 Online:2024-12-20 Published:2025-01-08

摘要: 为了提升低阶煤浮选效果,选取了酯类捕收剂,包括油酸甲酯(MeO)、月桂酸甲酯(MeL)和苯甲酸戊酯(nAB),作为组成复合捕收剂的成分,通过煤泥单元浮选试验研究了复合捕收剂对鄂尔多斯地区长焰煤的浮选效果。同时,利用分子动力学方法探究了复合酯类捕收剂与长焰煤之间的微观相互作用机理。研究结果表明,相较于传统的煤油捕收剂,酯类复合捕收剂能够显著提高长焰煤的浮选效果。在相同捕收剂用量条件下,三元复合捕收剂MeO/MeL/nAB的浮选效果明显优于二元复合捕收剂MeO/nAB或MeO/MeL。分子动力学模拟结果显示,与二元复合捕收剂MeO/nAB或MeO/MeL相比,三元复合捕收剂MeO/MeL/nAB与煤模型之间的相互作用强度更高。

关键词: 低阶煤, 浮选, 复合酯类捕收剂, 分子模拟

Abstract: The composite lipid collector was composed of methyl oleate (MeO), methyl laurate (MeL) and amyl benzoate (nAB) according to the mass ratio. The flotation effects of different types and amounts of composite lipid collectors on low-order long-flame coal were studied. The microscopic interaction mechanism between different types of composite collectors and low-order long-flame coal was investigated by molecular dynamics method. The results show that compared with traditional kerosene collectors, the composite lipid collector can significantly improve the floatation efficiency of low-rank long-flame coal, and the flotation efficiency of ternary composite MeO/MeL/nAB collector is significantly better than that of binary composite MeO/nAB or MeO/MeL collector at the same dosage. The adsorption mechanism of different lipid collectors on the coal surface was revealed by molecular dynamics simulation of the adsorption configuration of the collector and the interaction between the collector and the coal surface. Compared with the binary composite collector MeO/MeL and MeO/nAB, the interaction between the terpolymer collector MeO/MeL/nAB and the coal model was stronger, and the flotation effect of low-rank coal was better.